1.Product details:
Acrylic acid (IUPAC: prop-2-enoic acid) is an organic compound with the formula CH2=CHCO2H. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a characteristic acrid or tart smell. It is miscible with water, alcohols, ethers, and chloroform. More than a thousand kilotons are produced annually.
CAS NO. | 79-10-7 |
EINECS NO. | 201-177-9 |
MF | C3H4O2 |
Purity | 99.5% |
Appearance | Colorless liquid with characteristic acrid or tart smell. |
Melting Point | 14 °C (57 °F; 287 K) |
Boling Point | 141 °C (286 °F; 414 K) |
Flash Point | 130°F |
Solubility | Miscible |
Density | 1.051 g/mL |
Vapor pressure | 3 mmHg |
2.Production:
Acrylic acid is produced from propene which is a byproduct of ethylene and gasoline production.
CH2=CHCH3 + 1.5 O2→ CH2=CHCO2H + H2O
Because acrylic acid and its esters have long been valued commercially, many other methods have been developed but most have been abandoned for economic or environmental reasons. An early method was the hydrocarboxylation of acetylene ("Reppe chemistry"):
HCCH + CO + H2O → CH2=CHCO2H
This method requires nickel carbonyl and high pressures of carbon monoxide. It was once manufactured by the hydrolysis of acrylonitrile which is derived from propene by ammoxidation, but was abandoned because the method cogenerates ammonium derivatives. Other now abandoned precursors to acrylic acid include ethenone and ethylene cyanohydrin.
Dow Chemical Company and a partner, OPX Biotechnologies, are investigating using fermented sugar to produce 3-hydroxypropionic acid (3HP), an acrylic acid precursor. The goal is to reduce greenhouse gas emissions.
3.Stability:
Stability Unstable - may contain p-methoxyphenol as an inhibitor. Prone to hazardous polymerization. Combustible. Incompatible with strong oxidizing agents, strong bases, amines. Contact with oxidizers may cause fire. Light and air sensitive. Hygroscopic.
4.Package and Storage:
1). 200kgs/drum.500kgs/drum Other package according to client's requirement
2).Should be stored in original packaging in cool and dry place, away from sources of heat, flame and direct sunlight.
5.Specification:
Item | Specification | Result |
Appearance | clear ,colorless liquid | clear ,colorless liquid |
Content≥% | 99.5 | 99.6 |
Water Content≤% | 0.2 | 0.09 |
Color, Pt-Co≤ | 15 | 5 |
Specific Gravity | 1.047-1.052 | 1.05 |
Inhibitor (MEHQ), ppm | 200±20 | 205 |
6.Application:
Acrylic acid and its esters readily combine with themselves (to form polyacrylic acid) or other monomers (e.g. acrylamides, acrylonitrile, vinyl, styrene, and butadiene) by reacting at their double bond, forming homopolymers or copolymers which are used in the manufacture of various plastics, coatings, adhesives, elastomers, as well as floor polishes, and paints.
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